By Dan Luss and Vern W. Weekman, Jr. (Eds.)
content material: Chemical reactor modeling : the fascinating and the conceivable / R. Shinnar --
Liquid-supported catalysts / C.N. Kenney --
Coal conversion response engineering / C.Y. Wen and S. Tone --
delivery phenomena in packed mattress reactors / E.U. Schlünder --
Environmental response engineering / John H. Seinfeld --
The layout of gas-solids fluid mattress and comparable reactors / W.P.M. Van Swaaij --
Gas-liquid reactors / J.C. Charpentier --
Biochemical response engineering / Arthur E. Humphrey --
Catalyst deactivation / John B. Butt and Rustom M. Billimoria.
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Additional info for Chemical Reaction Engineering Reviews—Houston
The a p p l i c a t i o n o f the concept of model space and wnmding may provide a s t a r t i n g p o i n t . ch001 1) The only product promoted by the c a t a l y s t i s ammonia. The dimension o f Ζ i s always the most important informa t i o n contained i n and r e q u i r e s c a r e f u l checking f o r new c a t a l y s t s . 2) The r a t e i s a f u n c t i o n o f measurable c o n c e n t r a t i o n s . We know, o r b e l i e v e , t h a t intermediate s p e c i e s p l a y a r o l e .
The s i m i l a r i t i e s b e t w e e n c a t a l y s t s u s e d f o r o x i d a t i o n o f HC& a n d o x y c h l o r i n a t i o n o f o l e f i n s a r e a p p a r e n t f r o m t h e c a t a l y s t patents. A v e r y h i g h s e l e c t i v i t y (98-99%) f o r 1,2 d i c h l o r o e t h a n e i s s a i d t o b e o b t a i n e d a n d t h e c a t a l y s t c o n t a i n s CuC£2> a l k a l i m e t a l , r a r e e a r t h m e t a l s a n d sometimes s m a l l amounts o f o t h e r m e t a l s s u c h a s s i l v e r (21)(22) o r g o l d ( 2 3 ) .
A related type of catalyst which will not be discussed here i s the supported homogeneous catalyst where the active agent, usually a transition metal complex, i s actually bound chemically to the support, often a porous polymer matrix. It is fairly clear that with these latter systems the interaction between the catalyst and the support have important effects on modifying the catalyst proper ties which fortunately do not usually arise in the two, and sometimes three phase reaction systems which occur with SLP systems.